Kesterite Inorganic-Organic Heterojunction for Solution Processable Solar Cells
P. Data , Maciej Białogłowski , K. Lyzwa , Rajmund Bacewicz , P. Dluzewski , M. Łapkowski , T. Gregorkiewicz , Sławomir Podsiadło , Andrew Monkman
AbstractNew synthesis of solution processable kesterite and kesterite-phenoxazine nanopowders were presented. The direct band-gap semiconductor Cu2ZnSnS4 has attracted the attention of many due to its large absorption coefficient (α > 104 cm-1) and (optical) band-gap energy close to the optimal value for solar light conversion (1.4-1.6 eV). The presence of a kesterite nanocrystal structure has been investigated and confirmed by (HR)TEM, X-ray powder diffraction, EDX and EXAFS measurements. Low-temperature photoluminescence (PL) measurements indicate the absence of PL in the Cu2ZnSnS4 nanocrystals. Electrochemical studies helped to prove that an inorganic-organic heterojunction of nanokesterite-phenoxazine was obtained. Device studies showed a two fold improvement in efficiency upon addition of a kesterite or phenoxazines-kesterite layer. © 2016 Elsevier Ltd. All rights reserved.
|Journal series||Electrochimica Acta, ISSN 0013-4686|
|Publication size in sheets||0.5|
|Keywords in English||Electrochemistry; Energy gap; Nanocrystals; Solar cells; Temperature; X ray powder diffraction, Direct band gap semiconductors; Electrochemical studies; Inorganic-organic heterojunctions; Kesterites; Large absorption coefficient; Low temperature photoluminescence; P3HT; Phenoxazine, Heterojunctions|
|Score|| = 40.0, 10-01-2020, ArticleFromJournal|
= 40.0, 10-01-2020, ArticleFromJournal
|Publication indicators||= 3; = 1; : 2016 = 1.185; : 2016 = 4.798 (2) - 2016=4.63 (5)|
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