Dependence of a glass transition temperature on a heating rate in DTA experiments for glasses containing transition metal oxides

Przemysław Piotr Michalski , Tomasz Pietrzak , Jan Nowiński , Marek Wasiucionek , Jerzy Garbarczyk


It has been known for > 60 years that thermal events taking place during DTA measurements (e.g. glass transition or crystallization) depend on heating rate. In this paper, we collected numerous data of DTA measurements of various glasses containing transition metal oxides (V2O5, FeO, Ti2O3) carried out at different heating rates (1 to 25 °C/min). We showed that glass transition temperature vs. heating rate can be well described by both Kissinger's and Lasocka's formulas. Additionally, we discuss an accuracy of extrapolation based on data taken at high heating rates to low heating rates. Our result show that glass transition temperatures at low heating rates can be satisfactorily extrapolated from higher ones, with a relative error < 3.5% in every case (and mostly < 1%), due to linear change with heating rate both in Kissinger's and Lasocka's plots. © 2016 Elsevier B.V. All rights reserved.
Author Przemysław Piotr Michalski (FP / SSID)
Przemysław Piotr Michalski,,
- Solid State Ionics Division
, Tomasz Pietrzak (FP / SSID)
Tomasz Pietrzak,,
- Solid State Ionics Division
, Jan Nowiński (FP / SSID)
Jan Nowiński,,
- Solid State Ionics Division
, Marek Wasiucionek (FP / SSID)
Marek Wasiucionek,,
- Solid State Ionics Division
, Jerzy Garbarczyk (FP / SSID)
Jerzy Garbarczyk,,
- Solid State Ionics Division
Journal seriesJournal of Non-Crystalline Solids, ISSN 0022-3093
Issue year2016
Publication size in sheets0.5
Keywords in EnglishDifferential thermal analysis; Extrapolation; Glass; Heating; Heating rate; Metals; Temperature; Thermoanalysis; Titanium oxides; Transition metal compounds; Transition metals, DTA measurements; High heating rates; Kissinger; Lasocka's formula; Relative errors; Thermal events; Transition metal oxide glass; Transition-metal oxides, Glass transition
ASJC Classification2505 Materials Chemistry; 3104 Condensed Matter Physics; 2503 Ceramics and Composites; 2504 Electronic, Optical and Magnetic Materials
Languageen angielski
Score (nominal)30
Score sourcejournalList
ScoreMinisterial score = 30.0, 17-12-2019, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 17-12-2019, ArticleFromJournal
Publication indicators Scopus Citations = 5; WoS Citations = 3; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.155; WoS Impact Factor: 2016 = 2.124 (2) - 2016=1.926 (5)
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