Redox-controlled release of molecular payloads from multilayered organometallic polyelectrolyte films

Jing Song , Dominik Jańczewski , Yujie Ma , Mark Hempenius , Jianwei Xu , G. Julius Vancso

Abstract

Organometallic poly(ferrocenylsilane)s (PFSs) featuring redox responsive ferrocene units in their main chain are prepared and characterized for redox triggered film disassembly and release of molecular payloads. Positively or negatively charged side groups render PFS water soluble and these polyelectrolytes also allow the use of an electrostatic self-assembly process for the fabrication of novel functional supermolecular nanostructures. The layer-by-layer (LbL) electrostatic fabrication approach is utilized to obtain films with different bilayer numbers. The electrochemical behaviour of the multilayers with different thicknesses is recorded by capturing cyclic voltammograms (CVs). Film disassembly (multilayer re-dispersed in water) is performed by exposing the multilayers to the different values of holding potentials, corresponding to partial or full oxidation of PFS. Disassembly kinetics is quantitatively monitored by determining the amount of polymer released from CV experiments, as well as from UV-VIS spectroscopy. The proposed PFS multilayer disassembly mechanism is presented. The morphology of the multilayer films as a function of holding times is monitored by AFM. The release of guest molecules such as fluorescent Alexa dyes incorporated at different depths in the multilayer films is studied by fluorescence spectroscopy.
Author Jing Song - [A-Star, Institute of Materials Research and Engineering]
Jing Song,,
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, Dominik Jańczewski (FC / LTP) - [Institute of Materials Research and Engineering]
Dominik Jańczewski,,
- Laboratory Of Technological Processes
- Institute of Materials Research and Engineering
, Yujie Ma - [Radboud University Nijmegen]
Yujie Ma,,
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, Mark Hempenius - [MESA Institute for Nanotechnology]
Mark Hempenius,,
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, Jianwei Xu - [A-Star, Institute of Materials Research and Engineering]
Jianwei Xu,,
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, G. Julius Vancso - [MESA Institute for Nanotechnology]
G. Julius Vancso,,
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Journal seriesJournal of Materials Chemistry B: materials for biology and medicine, ISSN 2050-750X
Issue year2013
Vol1
No6
Pages828-834
Publication size in sheets0.5
Keywords in English organometallic polymer, ferrocene, controlled release, Layer by Layer
DOIDOI:10.1039/C2TB00092J
URL http://pubs.rsc.org/en/Content/ArticleLanding/2013/TB/c2tb00092j#!divAbstract
Internal identifier15/DJ
Languageen angielski
File
c2tb00092j.pdf 571.27 KB
Score (nominal)35
Score sourcejournalList
ScoreMinisterial score = 0.0, 31-01-2020, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 31-01-2020, ArticleFromJournal
Publication indicators Scopus Citations = 29; WoS Citations = 30; WoS Impact Factor: 2014 = 4.726 (2) - 2014=4.729 (5)
Citation count*17 (2015-04-21)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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